A Dragon Priest Mask is obtained after defeating each of the eight Dragon Priests that appear in locations throughout Skyrim.
Each mask has a unique color and made of different materials. The masks our named after its master, and has unique effects. The masks usually have three effects that increase your skills.
The priests are found close to Words of Power walls in coffins like other Draugr.
Read more to see the locations.
Mask Locations:
Volsung
Found at Volskygge in Haafingar
20% better prices, 20 more carrying capacity and gives you the ability to breathe underwater.
Vokun
Found at High Gate Ruins in The Pale
Conjuration, Illusion and Alterations spells cost 20% less to cast.
Otar
Found at Ragnvald in The Reach.
+30% Resistance against fire, frost and shock.
Morokei
Found at Labrynthian in Hjaalmarch.
Magicka regenerates 100% faster.
Rahgot
Found at Forelhost in The Rift
Increases stamina by 70 points.
Hevnoraak
Found at Valthume in The Reach
The wearer is immune to disease and poison.
Krosis
Found at Shearpoint in The Pale
Lockpicking, Archery, and Alchemy are 20% better.
Nahkriin
Found at Skuldafn – Only attainable prior to entering the portal to Sovngarde, during The World-Eater’s Eyrie quest.
+50 magicka, and destruction and restoration spell cost 20% less.
The Ninth Mask
After collecting the eight Dragon Priest masks proceed to the barrow in Labrynthian to find the Wooden Mask that sends you back in time to the Dragon Priest Shrine. Place the 8 masks in each slot to get the Konahrik mask.
Konahrik is the ninth Dragon Priest mask. When the wearer is low on health, there is a chance the mask will knock back enemies, heal the wearer and any nearby allies, and grant a fire cloak for a brief time. Also, on rare occasions, the mask will summon a spectral Dragon Priest to come to your aid.
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King Toko 
iv seen so many youtube videos on skyrim masks and id have to say vulsung is the best.
i went around to gather all the masks but for some reason hevnoraak didnt have a mask when i defeated him. i’m trying to figure out why now that im so far ahead wioth my favorite charecter! anyone that could help?
Sorry to hear that. The dragon priest Hevnoraak in Valthume should have the mask during the Evil In Waiting quest.